Compound, color conversion film comprising same, back-light unit, and display device

ABSTRACT

The present specification relates to a compound represented by Chemical Formula 1, and a color conversion film, a backlight unit and a display apparatus including the same.

This application is a 35 U.S.C. 371 National Phase Entry Application from PCT/KR2020/002726 filed on Feb. 26, 2020, designating the United States, which claims priority to and the benefits of Korean Patent Application No. 10-2019-0023888, filed with the Korean Intellectual Property Office on Feb. 28, 2019, the entire contents of which are incorporated herein by reference.

TECHNICAL FIELD

The present specification relates to a compound, and a color conversion film, a backlight unit and a display apparatus including the same.

BACKGROUND OF THE INVENTION

Existing light emitting diodes (LED) are obtained by mixing a green phosphorescent substance and a red phosphorescent substance to a blue light emitting diode, or mixing a yellow phosphorescent substance and a blue-green phosphorescent substance to a UV light emitting diode. However, with such a method, it is difficult to control colors, and therefore, color rendering is not favorable. Accordingly, color gamut declines.

In order to overcome such color gamut decline and to reduce production costs, methods of obtaining green and red in a manner of filming quantum dots and binding the dots to a blue LED have been recently tried. However, cadmium series quantum dots have safety problems, and other quantum dots have significantly decreased efficiency compared to cadmium series quantum dots. In addition, quantum dots have reduced stability for oxygen and water, and have a disadvantage in that the performance is significantly degraded when aggregated. Furthermore, unit costs of production are high since, when producing quantum dots, maintaining the sizes to be constant is difficult.

BRIEF SUMMARY OF THE INVENTION

The present specification is directed to providing a compound, and a color conversion film, a backlight unit and a display apparatus including the same.

One embodiment of the present specification provides a compound represented by the following Chemical Formula 1.

In Chemical Formula 1,

X is a direct bond; S; or O,

X₁ and X₂ are the same as or different from each other, and each independently O or S,

R₁ and R₆ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a substituted or unsubstituted alkyl group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted aryloxy group; or a substituted or unsubstituted heteroaryl group,

R₃ and R₄ are the same as or different from each other, and each independently a substituted or unsubstituted aryl group,

R₂ and R₅ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; —C(═O)OR_(A); —OC(═O)R_(B); a substituted or unsubstituted aryl group; or a substituted or unsubstituted heteroaryl group,

R₇ is a substituted or unsubstituted aryl group; a substituted or unsubstituted aryloxy group; a substituted or unsubstituted arylthioxy group; or a substituted or unsubstituted heteroaryl group,

R₈, R₁₀ to R₁₃ and R₁₅ are the same as or different from each other, and each independently hydrogen; deuterium; or a halogen group,

R₉ and R₁₀ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a nitro group; —C(═O)OR_(C); —OC(═O)R_(D); a substituted or unsubstituted alkyl group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted aryl group; or a substituted or unsubstituted heteroaryl group, and

R_(A) to R_(D) are the same as or different from each other, and each independently a substituted or unsubstituted alkyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted heteroaryl group; or a substituted or unsubstituted coumarin group.

Another embodiment of the present specification provides a color conversion film including a resin matrix; and the compound represented by Chemical Formula 1 dispersed into the resin matrix.

Another embodiment of the present specification provides a backlight unit including the color conversion film.

Another embodiment of the present specification provides a display apparatus including the backlight unit.

Advantageous Effects

A compound according to one embodiment of the present specification has more superior light resistance and heat resistance compared to existing compounds having a bodipy structure. Accordingly, by using the compound described in the present specification as a fluorescent material of a color conversion film, a color conversion film having excellent luminance and color gamut, and excellent durability can be provided.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a mimetic diagram using a color conversion film according to one embodiment of the present specification in a backlight unit.

FIG. 2 is a mimetic diagram illustrating a structure of a display apparatus according to one embodiment of the present specification.

DETAILED DESCRIPTION OF THE INVENTION

Hereinafter, the present application will be described in more detail.

One embodiment of the present specification provides a compound represented by Chemical Formula 1.

In the present specification, a certain part “including” certain constituents means capable of further including other constituents, and does not exclude other constituents unless particularly stated on the contrary.

In the present specification, one member being placed “on” another member includes not only a case of the one member being in contact with the another member but a case of still another member being present between the two members.

In the present specification, an “adjacent” group may mean a substituent substituting an atom directly linked to an atom substituted by the corresponding substituent, a substituent sterically most closely positioned to the corresponding substituent, or another substituent substituting an atom to substituted by the corresponding substituent. For example, two substituents substituting ortho positions in a benzene ring, and two substituents substituting the same carbon in an aliphatic ring may be interpreted as groups “adjacent” to each other.

Examples of substituents in the present specification are described below, however, the substituents are not limited thereto.

The term “substitution” means a hydrogen atom bonding to a carbon atom of a compound being changed to another substituent, and the position of substitution is not limited as long as it is a position at which the hydrogen atom is substituted, that is, a position at which a substituent can substitute, and when two or more substituents substitute, the two or more substituents may be the same as or different from each other.

The term “substituted or unsubstituted” in the present specification means being substituted with one, two or more substituents selected from the group consisting of deuterium; a halogen group; a cyano group; a nitro group; —C(═O)R; —C(═O)OR′; —OC(═O)R″; an imide group; an amide group; a hydroxyl group; a substituted or unsubstituted amine group; a substituted or unsubstituted silyl group; a substituted or unsubstituted alkyl group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted haloalkyl group; a substituted or unsubstituted alkoxy group; a substituted or unsubstituted alkenyl group; a substituted or unsubstituted alkynyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted aryloxy group; a substituted or unsubstituted arylthioxy group; a substituted or unsubstituted heterocyclic group and a substituted or unsubstituted coumarin group, or being substituted with a substituent linking two or more substituents among the substituents illustrated above, or having no substituents, and R, R′ and R″ are each independently a substituted or unsubstituted alkyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted heteroaryl group; or a substituted or unsubstituted coumarin group.

In the present specification, examples of the halogen group may include fluorine, chlorine, bromine or iodine.

In the present specification, the number of carbon atoms of the imide group is not particularly limited, but is preferably from 1 to 30.

In the present specification, in the amide group, nitrogen of the amide group may be substituted with hydrogen, a linear, branched or cyclic alkyl group having 1 to 30 carbon atoms, or an aryl group having 6 to 30 carbon atoms.

In the present specification, the amine group may be selected from the group consisting of —NH₂; a monoalkylamine group; a dialkylamine group; an N-alkylamine group; a monoarylamine group; a diarylamine group; an N-arylheteroarylamine group; an N-alkylheteroarylamine group, a monoheteroarylamine group and a diheteroarylamine group, and, although not particularly limited thereto, the number of carbon atoms is preferably from 1 to 30.

In the present specification, the N-alkylarylamine group means an amine group in which N of the amine group is substituted with an alkyl group and an aryl group.

In the present specification, the N-arylheteroarylamine group means an amine group in which N of the amine group is substituted with an aryl group and a heteroaryl group.

In the present specification, the N-alkylheteroarylamine group means an amine group in which N of the amine group is substituted with an alkyl group and a heteroaryl group.

In the present specification, the alkyl group in the alkylamine group, the N-alkylarylamine group, the alkylthioxy group, the alkylsulfoxy group and the N-alkylheteroarylamine group is the same as the examples of the alkyl group described above.

In the present specification, specific examples of the silyl group may include a trimethylsilyl group, a triethylsilyl group, a t-butyldimethylsilyl group, a vinyldimethylsilyl group, a propyldimethylsilyl group, a triphenylsilyl group, a diphenylsilyl group, a phenylsilyl group and the like, but are not limited thereto.

In the present specification, the alkyl group may be linear or branched, and although not particularly limited thereto, the number of carbon atoms is preferably from 1 to 30. Specific examples thereof may include methyl, ethyl, propyl, n-propyl, isopropyl, butyl, n-butyl, isobutyl, tert-butyl, sec-butyl, 1-methyl-butyl, 1-ethyl-butyl, pentyl, n-pentyl, isopentyl, neopentyl, tert-pentyl, hexyl, n-hexyl, methylpentyl, 2-methylpentyl, 4-methyl-2-pentyl, 3,3-dimethylbutyl, 2-ethylbutyl, heptyl, n-heptyl, methylhexyl, cyclopentylmethyl, cyclohexylmethyl, octyl, n-octyl, tert-octyl, 1-methylheptyl, ethylhexyl, 2-propylpentyl, n-nonyl, 2,2-dimethylheptyl, 1-ethyl-propyl, 1,1-dimethyl-propyl, isohexyl, 4-methylhexyl, 5-methylhexyl and the like, but are not limited thereto.

In the present specification, the cycloalkyl group is not particularly limited, but preferably has 3 to 30 carbon atoms, and specific examples thereof may include cyclopropyl, cyclobutyl, cyclopentyl, methylcyclopentyl, 2,3-dimethylcyclopentyl, cyclohexyl, 3-methylcyclohexyl, 4-methylcyclohexyl, 2,3-dimethylcyclohexyl, 3,4,5-trimethylcyclohexyl, 4-tert-butylcyclohexyl, cycloheptyl, cyclooctyl and the like, but are not limited thereto.

In the present specification, the haloalkyl group represents an alkyl group in which a hydrogen atom of the alkyl group is replaced by the same or a different halogen group. The haloalkyl group may be linear or branched, and although not particularly limited thereto, the number of carbon atoms is preferably from 1 to 10. Specific examples thereof may include —CH₂Cl, —CF₃, —CH₂CF₃, —CF₂CF₃ and the like, but are not limited thereto.

In the present specification, the alkoxy group may be linear, branched or cyclic. The number of carbon atoms of the alkoxy group is not particularly limited, but is preferably from 1 to 30.

In the present specification, the alkenyl group may be linear or branched, and although not particularly limited thereto, the number of carbon atoms is preferably from 2 to 30.

In the present specification, the alkynyl group may be linear or branched, and although not particularly limited thereto, the number of carbon atoms is preferably from 2 to 30. Specific examples thereof may include alkynyl groups such as ethynyl, propynyl, 2-methyl-2-propynyl, 2-butynyl, 2-pentynyl and the like, but are not limited thereto.

In the present specification, the aryl group is not particularly limited, but preferably has 6 to 30 carbon atoms, and the aryl group may be monocyclic or polycyclic.

When the aryl group is a monocyclic aryl group, the number of carbon atoms is not particularly limited, but is preferably from 6 to 30. Specific examples of the monocyclic aryl group may include a phenyl group, a biphenyl group, a terphenyl group and the like, but are not limited thereto.

When the aryl group is a polycyclic aryl group, the number of carbon atoms is not particularly limited, but is preferably from 10 to 30. Specific examples of the polycyclic aryl group may include a naphthyl group, an anthracenyl group, a phenanthryl group, a triphenyl group, a pyrenyl group, a perylenyl group, a chrysenyl group, a fluorenyl group and the like, but are not limited thereto.

In the present specification, the fluorenyl group may be substituted, and adjacent groups may bond to each other to form a ring.

When the fluorenyl group is substituted,

and the like may be included. However, the structure is not limited thereto.

In the present specification, the aryl group in the aryloxy group and the arylthioxy group is the same as the examples of the aryl group described above. Specific examples of the aryloxy group may include a phenoxy group, a p-tolyloxy group, an m-tolyloxy group, a 3,5-dimethyl-phenoxy group, a 2,4,6-trimethylphenoxy group, a p-tert-butylphenoxy group, a 3-biphenyloxy group, a 4-biphenyloxy group, a 1-naphthyloxy group, a 2-naphthyloxy group, a 4-methyl-1-naphthyloxy group, a 5-methyl-2-naphthyloxy group, a 1-anthryloxy group, a 2-anthryloxy group, a 9-anthryloxy group, a 1-phenanthryloxy group, a 3-phenanthryloxy group, a 9-phenanthryloxy group and the like, specific examples of the arylthioxy group may include a phenylthioxy group, a 2-methylphenylthioxy group, a 4-tert-butylphenylthioxy group and the like, however, the aryloxy group and the arylthioxy group are not limited thereto.

In the present specification, the heteroaryl group is a group including one or more atoms that are not carbon, that is, heteroatoms, and specifically, the heteroatom may include one or more atoms selected from the group consisting of O, N, Se, S and the like. The number of carbon atoms is not particularly limited, but is preferably from 2 to 30, and the heteroaryl group may be monocyclic or polycyclic. Examples of the heteroaryl group may include a thiophene group, a furanyl group, a pyrrole group, an imidazolyl group, a thiazolyl group, an oxazolyl group, an oxadiazolyl group, a pyridyl group, a bipyridyl group, a pyrimidyl group, a triazinyl group, a triazolyl group, an acridyl group, a pyridazinyl group, a pyrazinyl group, a quinolinyl group, a quinazolinyl group, a quinoxalinyl group, a phthalazinyl group, a pyridopyrimidyl group, a pyridopyrazinyl group, a pyrazinopyrazinyl group, an isoquinolinyl group, an indolyl group, a carbazolyl group, a benzoxazolyl group, a benzimidazolyl group, a benzothiazolyl group, a benzocarbazolyl group, a benzothiophene group, a dibenzothiophene group, a benzofuranyl group, a phenanthrolinyl group, a thiazolyl group, an isoxazolyl group, an oxadiazolyl group, a thiadiazolyl group, a phenothiazinyl group, a dibenzofuranyl group and the like, but are not limited thereto.

In the present specification, in the coumarin group, carbon of the coumarin group may be substituted with a halogen group; a nitrile group; a linear, branched or cyclic alkyl group having 1 to 25 carbon atoms; an amine group; a linear or branched alkoxy group having 1 to 25 carbon atoms; or an aryl group having 6 to 30 carbon atoms.

In one embodiment of the present specification, X is a direct bond; S; or O.

In one embodiment of the present specification, X is a direct bond.

In one embodiment of the present specification, X is S.

In one embodiment of the present specification, X is O.

In one embodiment of the present specification, X₁ and X₂ are the same as or different from each other, and each independently O or S.

In one embodiment of the present specification, X₁ and X₂ are O.

In one embodiment of the present specification, X₁ and X₂ are S.

In one embodiment of the present specification, R₁ and R₆ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a substituted or unsubstituted alkyl group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted aryloxy group; or a substituted or unsubstituted heteroaryl group.

In one embodiment of the present specification, R₁ and R₆ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted aryloxy group; or a substituted or unsubstituted heteroaryl group.

In one embodiment of the present specification, R₁ and R₆ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a substituted or unsubstituted C3 to C30 cycloalkyl group; a substituted or unsubstituted C6 to C30 aryl group; or a substituted or unsubstituted C6 to C30 aryloxy group.

In one embodiment of the present specification, R₁ and R₆ are the same as or different from each other, and each independently hydrogen; deuterium; a cycloalkyl group unsubstituted or substituted with an alkyl group; or an aryloxy group unsubstituted or substituted with a halogen group.

In one embodiment of the present specification, R₁ and R₆ are the same as or different from each other, and each independently hydrogen; deuterium; a cyclohexyl group unsubstituted or substituted with an alkyl group; or an aryloxy group unsubstituted or substituted with a halogen group.

In one embodiment of the present specification, R₁ and R₆ are the same as or different from each other, and each independently hydrogen; deuterium; a cyclohexyl group unsubstituted or substituted with an alkyl group; or a C6 to C20 aryloxy group unsubstituted or substituted with a halogen group.

In one embodiment of the present specification, R₁ and R₆ are the same as each other, and are hydrogen; deuterium; a halogen group; a cyano group; a substituted or unsubstituted cyclohexyl group; or a substituted or unsubstituted C6 to C20 aryloxy group.

In one embodiment of the present specification, one of R₁ and R₆ is hydrogen, and the other one is a halogen group; a cyano group; a substituted or unsubstituted cyclohexyl group; or a substituted or unsubstituted C6 to C20 aryloxy group.

In one embodiment of the present specification, R₃ and R₄ are the same as or different from each other, and each independently a substituted or unsubstituted aryl group.

In one embodiment of the present specification, R₃ and R₄ are the same as or different from each other, and each independently an aryl group unsubstituted or substituted with one or more substituents selected from the group consisting of a halogen group, a cyano group and an alkyl group.

In one embodiment of the present specification, R₃ and R₄ are the same as or different from each other, and each independently a C6 to C20 aryl group unsubstituted or substituted with one or more substituents selected from the group consisting of a halogen group, a cyano group and an alkyl group.

In one embodiment of the present specification, R₃ and R₄ are the same as or different from each other, and each independently a phenyl group unsubstituted or substituted with one or more substituents selected from the group consisting of a halogen group, a cyano group and an alkyl group.

In one embodiment of the present specification, R₃ and R₄ are the same as or different from each other, and each independently an aryl group unsubstituted or substituted with one or more substituents selected from the group consisting of a halogen group, a cyano group and a C1 to C10 alkyl group.

In one embodiment of the present specification, X₁ and X₂ are O, and R₃ and R₄ are the same as or different from each other and each independently an aryl group unsubstituted or substituted with one or more substituents selected from the group consisting of a halogen group, a cyano group and an alkyl group.

In one embodiment of the present specification, X₁ and X₂ are S, and R₃ and R₄ are the same as or different from each other and each independently an aryl group unsubstituted or substituted with one or more substituents selected from the group consisting of a halogen group, a cyano group and an alkyl group.

In one embodiment of the present specification, R₂ and R₅ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; —C(═O)OR_(A); —OC(═O)R_(B); a substituted or unsubstituted aryl group; or a substituted or unsubstituted heteroaryl group.

In one embodiment of the present specification, R₂ and R₅ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; —C(═O)OR_(A); —OC(═O)R_(B); a substituted or unsubstituted C6 to C60 aryl group; or a substituted or unsubstituted C2 to C60 heteroaryl group.

In one embodiment of the present specification, R₂ and R₅ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; —C(═O)OR_(A); —OC(═O)R_(B); a substituted or unsubstituted C6 to C30 aryl group; or a substituted or unsubstituted C2 to C30 heteroaryl group.

In one embodiment of the present specification, R₂ and R₅ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; —C(═O)OR_(A); —OC(═O)R_(B); a substituted or unsubstituted C6 to C20 aryl group; or a substituted or unsubstituted C2 to C20 heteroaryl group.

In one embodiment of the present specification, R₂ and R₅ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; —C(═O)OR_(A); —OC(═O)R_(B); or an aryl group unsubstituted or substituted with a haloalkyl group.

In one embodiment of the present specification, R₂ and R₅ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; —C(═O)OR_(A); —OC(═O)R_(B); or a C6 to C20 aryl group unsubstituted or substituted with a haloalkyl group.

In one embodiment of the present specification, R₂ and R₅ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; —C(═O)OR_(A); —OC(═O)R_(B); or a phenyl group unsubstituted or substituted with a haloalkyl group.

In one embodiment of the present specification, R₂ and R₅ are the same as each other, and are hydrogen; deuterium; a halogen group; a cyano group; —C(═O)OR_(A); —OC(═O)R_(B); or a phenyl group unsubstituted or substituted with a haloalkyl group.

In one embodiment of the present specification, one of R₂ and R₅ is hydrogen, and the other one is a halogen group; a cyano group; —C(═O)OR_(A); —OC(═O)R_(B); or a substituted or unsubstituted alkyl group.

In one embodiment of the present specification, one of R₂ and R₅ is hydrogen, and the other one is —C(═O)OR_(A) or —OC(═O)R_(B).

In one embodiment of the present specification, one of R₂ and R₅ is a halogen group, and the other one is a cyano group; —C(═O)OR_(A); —OC(═O)R_(B); or a substituted or unsubstituted alkyl group.

In one embodiment of the present specification, one of R₂ and R₅ is a halogen group, and the other one is —C(═O)OR_(A) or —OC(═O)R_(B).

In one embodiment of the present specification, R_(A) and R_(B) are the same as or different from each other, and each independently a substituted or unsubstituted alkyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted heteroaryl group; or a substituted or unsubstituted coumarin group.

In one embodiment of the present specification, R_(A) and R_(B) are a substituted or unsubstituted coumarin group.

In one embodiment of the present specification, R₇ is a substituted or unsubstituted aryl group; a substituted or unsubstituted aryloxy group; a substituted or unsubstituted arylthioxy group; or a substituted or unsubstituted heteroaryl group.

In one embodiment of the present specification, R₇ is a substituted or unsubstituted C6 to C30 aryl group; a substituted or unsubstituted C6 to C30 aryloxy group; a substituted or unsubstituted C6 to C30 arylthioxy group; or a substituted or unsubstituted C6 to C30 heteroaryl group.

In one embodiment of the present specification, R₇ is an aryl group unsubstituted or substituted with one or more substituents selected from the group consisting of an alkyl group, a haloalkyl group and an alkoxy group; an aryloxy group unsubstituted or substituted with one or more substituents selected from the group consisting of a cyano group and an alkyl group; or a substituted or unsubstituted dibenzofuran group.

In one embodiment of the present specification, R₇ is a C6 to C30 aryl group unsubstituted or substituted with one or more substituents selected from the group consisting of an alkyl group, a haloalkyl group and an alkoxy group; a C6 to C30 aryloxy group unsubstituted or substituted with one or more substituents selected from the group consisting of a cyano group and an alkyl group; or a substituted or unsubstituted dibenzofuran group.

In one embodiment of the present specification, R₇ is a phenyl group unsubstituted or substituted with one or more substituents selected from the group consisting of an alkyl group, a haloalkyl group and an alkoxy group; an aryloxy group unsubstituted or substituted with one or more substituents selected from the group consisting of a cyano group and an alkyl group; or a dibenzofuran group.

In one embodiment of the present specification, R₈, R₁₀ to R₁₃ and R₁₅ are the same as or different from each other, and each independently hydrogen; deuterium; or a halogen group.

In one embodiment of the present specification, R₈, R₁₀ to R₁₃ and R₁₅ are the same as each other, and are hydrogen; deuterium; or a halogen group.

In one embodiment of the present specification, R₈, R₁₀ to R₁₃ and R₁₅ are hydrogen.

In one embodiment of the present specification, R₈, R₁₀ to R₁₃ and R₁₅ are deuterium.

In one embodiment of the present specification, R₈, R₁₀ to R₁₃ and R₁₅ are a halogen group.

In one embodiment of the present specification, R₈, R₁₀ to R₁₃ and R₁₅ are a fluoro group.

In one embodiment of the present specification, R₉ and R₁₀ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a nitro group; —C(═O)OR_(C); —OC(═O)R_(D); a substituted or unsubstituted alkyl group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted aryl group; or a substituted or unsubstituted heteroaryl group.

In one embodiment of the present specification, R₉ and R₁₄ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a nitro group; —C(═O)OR_(C); —OC(═O)R_(D); a substituted or unsubstituted alkyl group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted aryl group; or a substituted or unsubstituted heteroaryl group.

In one embodiment of the present specification, R₉ and R₁₄ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; or a substituted or unsubstituted alkyl group.

In one embodiment of the present specification, R₉ and R₁₄ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; or a substituted or unsubstituted C1 to C20 alkyl group.

In one embodiment of the present specification, R₉ and R₁₄ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; or a substituted or unsubstituted C1 to C10 alkyl group.

In one embodiment of the present specification, R_(C) and R_(D) are the same as or different from each other, and each independently a substituted or unsubstituted alkyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted heteroaryl group; or a substituted or unsubstituted coumarin group.

In one embodiment of the present specification, the compound represented by Chemical Formula 1 is represented by any one of the following compounds.

In the compounds, iPr is isopropyl, and tBu is tert-butyl.

One embodiment of the present specification provides a color conversion film including a resin matrix; and the compound dispersed into the resin matrix.

According to one embodiment of the present specification, the compound of Chemical Formula 1 may be included in 0.01 parts by weight to 5 parts by weight, 0.01 parts by weight to 3 parts by weight, and 0.05 parts by weight to 1 parts by weight with respect to 100 parts by weight of the resin matrix.

When using a light source emitting light in a 430 nm to 470 nm region, the color conversion film according to the present specification has a maximum emission peak having a full width at half maximum of 50 nm or less in a 520 nm to 560 nm region. The light source may be, for example, a blue LED, but is not limited thereto. The full width at half maximum means, when converting light absorbed from an external light source to light having another wavelength and emitting the light, a width of the emission peak at half the maximum height in the maximum emission peak of the emitted light, and color gamut is excellent as the full width at half maximum is smaller.

The maximum emission peak and the full width at half maximum may be obtained by measuring a luminance spectrum using a spectroradiometer after laminating the color conversion film described above on one surface of a light guide plate of a backlight unit first, and laminating a prism sheet and a DBEF film on the color conversion film.

The content of the compound in the color conversion film may be in a range of 0.001% by weight to 15% by weight, and preferably in a range of 0.001% by weight to 10% by weight. When the content of the compound is in the above-mentioned range, a color conversion film having a uniform composition may be prepared.

The color conversion film may include one type of the compound, or may include two or more types thereof. For example, the color conversion film may include one type of the compound emitting green light among the compounds represented by Chemical Formula 1. As another example, the color conversion film may include one type of the compound emitting red light among the compounds represented by Chemical Formula 1. As another example, the color conversion film may include one type of the compound emitting green light and one type of the compound emitting red light among the compounds represented by Chemical Formula 1.

The color conversion film may further include additional fluorescent materials in addition to the compound represented by Chemical Formula 1. When using a light source emitting blue light, the color conversion film preferably includes both a green light emitting fluorescent material and a red light emitting fluorescent material. In addition, when using a light source emitting blue light and green light, the color conversion film may only include a red light emitting fluorescent material. However, the color conversion film is not limited thereto, and even when using a light source emitting blue light, the color conversion film may only include a red light emitting compound when a separate film including a green light emitting fluorescent material is laminated. On the other hand, even when using a light source emitting blue light, the color conversion film may only include a green light emitting compound when a separate film including a red light emitting fluorescent material is laminated.

The color conversion film may further include an additional layer including a resin matrix; and a compound dispersed into the resin matrix and emitting light in a wavelength different from the wavelength of the compound represented by Chemical Formula 1. The compound emitting light in a wavelength different from the wavelength of the compound represented by Chemical Formula 1 may also be the compound represented by Chemical Formula 1, or may be other known fluorescent materials.

The resin matrix material is preferably a thermoplastic polymer or a thermocurable polymer. Specifically, a poly(meth)acryl-based such as polymethyl methacrylate (PMMA), a polycarbonate (PC)-based, a polystyrene (PS)-based, a polyarylene (PAR)-based, a polyurethane (PU)-based, a styrene-acrylonitrile (SAN)-based, a polyvinylidene fluoride (PVDF)-based, a modified polyvinylidene fluoride (modified-PVDF)-based and the like may be used as the resin matrix material.

According to one embodiment of the present specification, the color conversion film according to the embodiments described above additionally includes light diffusing particles. By dispersing light diffusing particles into the color conversion film instead of a light diffusing film used in the art for enhancing luminance, higher luminance may be exhibited compared to using a separate light diffusing film, and an adhering process may be skipped as well.

As the light diffusing particles, particles having a high refractive index with the resin matrix may be used, and examples thereof may include TiO₂, silica, borosilicate, alumina, sapphire, air or other air-filled hollow beads or particles (for example, air/gas-filled glass or polymers); polystyrene, polycarbonate, polymethyl methacrylate, acryl, methyl methacrylate, styrene, a melamine resin, a formaldehyde resin, or polymer particles including melamine and formaldehyde resins, or any suitable combination thereof.

The light diffusing particles may have particle diameters in a range of 0.1 μm to 5 μm, for example, in a range of 0.3 μm to 1 μm. The content of the light diffusing particles may be determined as necessary, and for example, may be in a range of approximately 1 part by weight to 30 parts by weight based on 100 parts by weight of the resin matrix.

The color conversion film according to the embodiments described above may have a thickness of 2 μm to 200 μm. Particularly, the color conversion film may exhibit high luminance even with a small thickness of 2 μm to 20 μm. This is due to the fact that the content of the fluorescent material molecules included in the unit volume is higher compared to quantum dots.

The color conversion film according to the embodiments described above may have a substrate provided on one surface. This substrate may function as a support when preparing the color conversion film. Types of the substrate are not particularly limited, and the material or thickness is not limited as long as it is transparent and is capable of functioning as the support. Herein, being transparent means having visible light transmittance of 70% or higher. For example, a PET film may be used as the substrate.

The color conversion film described above may be prepared by coating a resin solution in which the compound represented by Chemical Formula 1 described above is dissolved on a substrate and drying the result, or by extruding and filming the compound represented by Chemical Formula 1 described above with a resin.

The compound represented by Chemical Formula 1 described above is dissolved in the resin solution, and therefore, the compound represented by Chemical Formula 1 is homogeneously distributed in the solution. This is different from a quantum dot film preparation process that requires a separate dispersion process.

As for the resin solution in which the compound represented by Chemical Formula 1 is dissolved, the preparation method is not particularly limited as long as the compound represented by Chemical Formula 1 described above and the resin are dissolved in the solution.

According to one example, the resin solution in which the compound represented by Chemical Formula 1 is dissolved may be prepared using a method of preparing a first solution by dissolving the compound represented by Chemical Formula 1 in a solvent, preparing a second solution by dissolving a resin in a solvent, and mixing the first solution and the second solution. When mixing the first solution and the second solution, it is preferred that these be homogeneously mixed. However, the method is not limited thereto, and a method of simultaneously adding and dissolving the compound represented by Chemical Formula 1 and a resin in a solvent, a method of dissolving the compound represented by Chemical Formula 1 in a solvent and subsequently adding and dissolving a resin, a method of dissolving a resin in a solvent and then subsequently adding and dissolving the compound represented by Chemical Formula 1, and the like, may be used.

As the resin included in the solution, the resin matrix material described above, a monomer curable to this resin matrix resin, or a mixture thereof, may be used. For example, the monomer curable to the resin matrix resin includes a (meth)acryl-based monomer, and this may be formed to a resin matrix material by UV curing. When using such a curable monomer, an initiator required for curing may be further added as necessary.

The solvent is not particularly limited as long as it is capable of being removed by drying afterword while having no adverse effects on the coating process.

Non-limiting examples of the solvent may include toluene, xylene, acetone, chloroform, various alcohol-based solvents, methyl ethyl ketone (MEK), methyl isobutyl ketone (MIBK), ethyl acetate (EA), butyl acetate, dimethylformamide (DMF), dimethylacetamide (DMAc), dimethyl sulfoxide (DMSO), N-methyl-pyrrolidone (NMP) and the like, and one type or a mixture of two or more types may be used. When using the first solution and the second solution, solvents included in each of the solutions may be the same as or different from each other. Even when different types of solvents are used in the first solution and the second solution, these solvents preferably have compatibility so as to be mixed with each other.

The process of coating the resin solution in which the compound represented by Chemical Formula 1 is dissolved on a substrate may use a roll-to-roll process. For example, a process of unwinding a substrate from a substrate-wound roll, coating the resin solution in which the compound represented by Chemical Formula 1 is dissolved on one surface of the substrate, drying the result, and then winding the result again on the roll may be used. When a roll-to-roll process is used, viscosity of the resin solution is preferably determined in a range capable of conducting the process, and for example, may be determined in a range of 200 cps to 2,000 cps.

As the coating method, various known methods may be used, and for example, a die coater may be used, or various bar coating methods such as a comma coater and a reverse comma coater may be used.

After the coating, a drying process is conducted. The drying process may be conducted under a condition required to remove a solvent. For example, a color conversion film including a fluorescent material including the compound represented by Chemical Formula 1 having target thickness and concentration may be obtained on a substrate by carrying out the drying in an oven located close to a coater under a condition to sufficiently evaporate a solvent, in a direction of the substrate progressing during the coating process.

When a monomer curable to the resin matrix resin is used as the resin included in the solution, curing, for example, UV curing, may be conducted prior to or at the same time as the drying.

When the compound represented by Chemical Formula 1 is filmed by being extruded with a resin, extrusion methods known in the art may be used, and for example, the color conversion film may be prepared by extruding the compound represented by Chemical Formula 1 with a resin such as a polycarbonate (PC)-based, a poly(meth)acryl-based and a styrene-acrylonitrile (SAN)-based.

According to one embodiment of the present specification, the color conversion film may have a protective film or a bather film provided on at least one surface. As the protective film or the bather film, those known in the art may be used.

One embodiment of the present specification provides a backlight unit including the color conversion film including the compound represented by Chemical Formula 1. The backlight unit may have backlight unit constitutions known in the art except for including the color conversion film. FIG. 1 illustrates a mimetic diagram of a backlight unit structure according to one embodiment. According to FIG. 1, the color conversion film including the compound represented by Chemical Formula 1 is provided on a surface opposite to a surface facing a reflecting plate of a light guide plate. FIG. 1 illustrates a constitution including a light source and a reflecting plate surrounding the light source, however, the constitution is not limited to such a structure, and may vary depending on the backlight unit structure known in the art. In addition, as the light source, a direct type as well as a side chain type may be used, and the reflecting plate or the reflective layer may not be included or may be replaced with other constituents as necessary, and as necessary, additional films such as a light diffusing film, a light concentrating film and a luminance enhancing film may be further provided. Preferably, a prism sheet, a multilayer reflective polarizer film, a light concentrating film or a luminance enhancing film is further provided on the color conversion film.

In the constitution of the backlight unit as in FIG. 1, a scattering pattern may be provided as necessary on an upper surface or a lower surface of the light guide plate. Light introduced into the light guide plate has non-uniform light distribution due to repetition of optical processes such as reflection, total reflection, refraction or transmission, and the scattering pattern may be used to induce the non-uniform light distribution to uniform brightness.

One embodiment of the present specification provides a display apparatus including the backlight unit. The display apparatus is not particularly limited as long as it includes the backlight unit. For example, the display apparatus includes a display module and a backlight unit. FIG. 2 illustrates a structure of the display apparatus. However, the structure is not limited thereto, and between the display module and the backlight unit, additional films such as a light diffusing film, a light concentrating film and a luminance enhancing film may be further provided as necessary.

Hereinafter, the present specification will be described in detail with reference to examples. However, the examples according to the present specification may be modified to various other forms, and the scope of the present specification is not to be construed as being limited to the examples to described below. Examples of the present specification are provided in order to more fully describe the present specification to those having average knowledge in the art.

Preparation Example 1

Synthesis of Compound 1-1

After mixing pyrrole (10 g), benzaldehyde (0.52 equivalents), trifluoroacetic acid (2 drops) and dry tetrahydrofuran (100 mL) in a flask, the mixture was stirred for 5 hours at room temperature under nitrogen. After identifying that the starting materials disappeared using TLC, bromine (1.0 equivalents) was added thereto at −78° C. After the reaction was completed, triethylamine (3 equivalents) and ethanol were introduced thereto, and the result was thoroughly stirred. Solids produced herein were filtered to obtain Compound 1-1 (14.8 g, yield 52%).

Synthesis of Compound 1-2

Compound 1-1 (14.8 g) was dissolved in chloroform, and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) (1.0 equivalents) was added thereto at 0° C. The result was stirred for 1 hour at room temperature, and then triethylamine (2.0 equivalents) was slowly added dropwise thereto. After stirring the result for 30 minutes at room temperature, 10-bromo-9-oxa-10-borane anthracene (4.0 equivalents) was slowly added dropwise thereto. The reaction material was stirred for 5 hours at room temperature, and, after introducing water thereto, extracted with dichloromethane. The result was dried with anhydrous magnesium sulfate, then filtered, and vacuum distilled to remove the solvent. The result was passed through a silica gel column (hexane/ethyl acetate) to obtain Compound 1-2 (15.9 g, yield 73%).

Synthesis of Compound 1

Compound 1-2 (3 g), 2,6-diisopropyl-4-cyanophenol (4 equivalents) and potassium carbonate (7 equivalents) were introduced to a dimethylformamide solvent, and thoroughly stirred. The reaction material was stirred for 12 hours at 80° C., and, after introducing water thereto, extracted with dichloromethane. The result was dried with anhydrous magnesium sulfate, then filtered, and vacuum distilled to remove the solvent. The result was passed through a silica gel column (hexane/ethyl acetate) to obtain Compound 1 (2.6 g, yield 60%). (HR LC/MS/MS m/z calculated for C₅₃H₄₉BN₄O₃ (M+): 800.3898; found: 800.3908)

Preparation Example 2

Synthesis of Compound 2-1

After dissolving Compound 1 (2.0 g) in a dichloromethane solvent, chlorosulfonyl isocyanate (3 equivalents) was introduced thereto. The reaction was progressed at room temperature, and the reaction was identified after taking out a small amount and mixing with dimethylformamide. When the reaction was finished, dimethylformamide (10 equivalents) was introduced thereto, and the result was stirred for approximately 3 hours. The result was extracted using water and chloroform, and then the organic layer was dried using sodium sulfate and purified to solids using methanol to obtain Compound 2-1 (1.8 g, yield 87%).

Synthesis of Compound 2

Compound 2-1 (1.8 g), cyclohexyl trifluoroborate potassium salt (2.5 equivalents) and manganese acetate hydrate (5 equivalents) were introduced to a dimethylformamide solvent, and heated to 80° C. or less. When the reaction was finished, the result was cooled to room temperature, and, after introducing water thereto, filtered with a celite pad. The celite pad was dissolved again in tetrahydrofuran, then dried by introducing sodium sulfate thereto, and then filtered. The result was vacuumed to remove the solvent, and purified to solids using methanol. Compound 2 (1.5 g, yield 68%) was obtained therethrough. (HR LC/MS/MS m/z calculated for C₆₈H₇₂BN₅O₃ (M+): 1017.5728; found: 1017.5713)

Preparation Example 3

Synthesis of Compound 3-1

After mixing pyrrole (10 g), benzaldehyde (0.52 equivalents), trifluoroacetic acid (2 drops) and dry dichloromethane (500 mL) in a flask, the mixture was stirred for 5 hours at room temperature under nitrogen. After identifying that the starting materials disappeared using TLC, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) (0.52 equivalents) was added thereto at 0° C. After stirring the result for 1 hour at room temperature, triethylamine (2.5 equivalents) was slowly added dropwise thereto. The result was stirred for 30 minutes at room temperature, and then 5-bromo-5H-dibenzoborole (4.6 equivalents) was slowly added dropwise thereto. The reaction material was stirred for 5 hours at mom temperature, and, after introducing water thereto, extracted with dichloromethane. The result was dried with anhydrous magnesium sulfate, then filtered, and vacuum distilled to remove the solvent. The result was passed through a silica gel column (hexane/ethyl acetate) to obtain Compound 3-1 (15.5 g, yield 54%).

Synthesis of Compound 3-2

After thoroughly mixing Compound 3-1 (5 g) in dichloromethane, the reaction was maintained at 0° C. Bromine (10 equivalents) was added thereto while maintaining 0° C. After the reaction was completed, the result was washed with a saturated sodium thiosulfate solution, dried with anhydrous magnesium sulfate and then silica filtered. The result was vacuum distilled to remove the solvent, and then passed through a silica gel column (hexane/ethyl acetate) to obtain Compound 3-2 (8.5 g, yield 93%).

Synthesis of Compound 3-3

Synthesis was conducted in the same manner as in Synthesis of Compound 1 except that Compound 3-2 was used instead of Compound 1-2. Compound 3-3 (3.1 g, yield 77%) was obtained therethrough.

Synthesis of Compound 3

Compound 3-3 (3.1 g) and 2,4-bis(trifluoromethyl)phenylboronic acid (4.2 equivalents) were dissolved in a tetrahydrofuran solvent, and stirred together with potassium carbonate (10 equivalents) dissolved in water. The result was heated to 80° C., then tetrakis triphenylphosphine palladium (1.0 equivalents) was introduced thereto, and when the reaction was finished, the result was extracted using water and chloroform. The organic layer was dried using sodium sulfate, and purified to solids using methanol. Compound 3 (2.9 g, yield 64%) was obtained therethrough. (HR LC/MS/MS m/z calculated for C₈₁H₇₃BF₁₂N₄O₂ (M+): 1372.5635; found: 1372.5621)

Preparation Example 4

Synthesis of Compound 4-1

Triphosgene (0.3 equivalents) was dissolved in dichloroethane, the result was introduced to pyrrole (5 g, 1 equivalents, 72 mmol), and, after further introducing triethylamine (0.1 equivalents) dissolved in dichloroethane thereto at 0° C. and under the nitrogen atmosphere, kept for 2 hours. After that, pyrrole (1 equivalents) was further introduced thereto, and the result was heated for 30 minutes at approximately 80° C. When the reaction was finished, diethyl ether was introduced thereto, and the result was separated using water. The organic layer was dried with sodium sulfate, and then column separated using silica gel. Compound 4-1 (4.0 g, yield 35%) was obtained therethrough.

Synthesis of Compound 4-2

After dissolving Compound 4-1 (4.0 g) in dichloroethane, POCl₃ (2 equivalents) was introduced thereto, and the result was heated for 3 hours. After the reaction was finished, the result was cooled to mom temperature, and, after introducing triethylamine (10 equivalents) thereto, left briefly at 0° C. 10-Bromo-9-thia-10-borane anthracene (11 equivalents) was slowly introduced thereto, and the result was further stirred for approximately 2 hours at mom temperature. After the reaction was finished, the mixture was extracted using diethyl ether and water. The organic layer was dried with sodium sulfate, and filtered using a silica pad to obtain target Compound 4-2 (4.9 g, yield 53%).

Synthesis of Compound 4-3

After dissolving Compound 4-2 (4.9 g) in dichloroethane, 2,6-diisopropylphenol (1.2 equivalents) and potassium carbonate (3 equivalents) were introduced thereto. The result was stirred at room temperature under the nitrogen atmosphere. After the reaction was completed, the result was extracted using diethyl ether and a sodium carbonate solution. The organic layer was dried with sodium sulfate, and then purified through a silica gel column to obtain Compound 4-3 (8.3 g, yield 88%).

Synthesis of Compound 4-4

Synthesis was conducted in the same manner as in Synthesis of Compound 3-2 except that Compound 4-3 was used instead of Compound 3-1. Compound 4-4 (12.0 g, yield 90%) was obtained therethrough.

Synthesis of Compound 4

Synthesis was conducted in the same manner as in Synthesis of Compound 1 except that Compound 4-4 was used instead of Compound 1-2, and 2,4,6-tri-fluorophenol was used instead of 2,6-diisopropyl-4-cyanophenol. Compound 4 (10.1 g, yield 72%) was obtained therethrough. (HR LC/MS/MS m/z calculated for C₄₅H₃₁BBr₂F₆N₂O₃S (M+): 962.0419; found: 962.0428)

Preparation Example 5

Synthesis of Compound 5-1

Synthesis was conducted in the same manner as in Synthesis of Compound 4-2 except that 10-bromo-9-oxa-10-borane anthracene was used instead of 10-bromo-9-thia-10-borane anthracene. Compound 5-1 (4.7 g, yield 53%) was obtained therethrough.

Synthesis of Compound 5-2

Synthesis was conducted in the same manner as in Synthesis of Compound 4-3 except that Compound 5-1 was used instead of Compound 4-2, and mesitol (2,4,6-trimethylphenol) was used instead of 2,6-diisopropylphenol. Compound 5-2 (5.1 g, yield 85%) was obtained therethrough.

Synthesis of Compound 5-3

Synthesis was conducted in the same manner as in Synthesis of Compound 3-2 except that Compound 5-2 was used instead of Compound 3-1. Compound 5-3 (7.7 g, yield 89%) was obtained therethrough.

Synthesis of Compound 5-4

Synthesis was conducted in the same manner as in Synthesis of Compound 1 except that Compound 5-3 was used instead of Compound 1-2, and 2,4,6-tri-fluorophenol was used instead of 2,6-diisopropyl-4-cyanophenol. Compound 5-4 (7.3 g, yield 81%) was obtained therethrough.

Synthesis of Compound 5

Synthesis was conducted in the same manner as in Synthesis of Compound 3 except that Compound 5-4 was used instead of Compound 3-3. Compound 5 (6.8 g, yield 72%) was obtained therethrough. (HR LC/MS/MS m/z calculated for C₅₈H₃₁BF₁₈N₂O₄ (M+): 1172.2089; found: 1172.2079)

Preparation Example 6

Synthesis of Compound 6-1

Synthesis was conducted in the same manner as in Synthesis of Compound 1-1 except that 3,5-ditrifluoromethyl benzaldehyde was used instead of benzaldehyde. Compound 6-1 (13.5 g, yield 35%) was obtained therethrough.

Synthesis of Compound 6-2

Synthesis was conducted in the same manner as in Synthesis of Compound 1-2 except that Compound 6-1 was used instead of Compound 1-1. Compound 6-2 (5.4 g, yield 60%) was obtained therethrough.

Synthesis of Compound 6

Synthesis was conducted in the same manner as in Synthesis of Compound 1 except that Compound 6-2 was used instead of Compound 1-2, and 2,6-dichlorobenzenethiol was used instead of 2,6-diisopropyl-4-cyanophenol. Compound 6 (3.9 g, yield 56%) was obtained therethrough. (HR LC/MS/MS m/z calculated for C₄₁H₂₁BCl₄F₆N₂OS₂ (M+): 885.9847; found: 885.9861)

Preparation Example 7

Synthesis of Compound 7-1

Synthesis was conducted in the same manner as in Synthesis of Compound 1-2 except that Compound 6-1 was used instead of Compound 1-1, and 10-bromo-9-thia-10-borane anthracene was used instead of 10-bromo-9-oxa-10-borane anthracene. Compound 7-1 (5.5 g, yield 59%) was obtained therethrough.

Synthesis of Compound 7-2

Synthesis was conducted in the same manner as in Synthesis of Compound 1 except that Compound 7-1 was used instead of Compound 1-2, and 2,6-dichlorobenzenethiol was used instead of 2,6-diisopropyl-4-cyanophenol. Compound 7-2 (5.8 g, yield 83%) was obtained therethrough.

Synthesis of Compound 7

After dissolving Compound 7-2 (5.8 g) in dimethylformamide, N-iodosuccinimide (NIS) (6 equivalents) was slowly introduced thereto at room temperature. The result was stirred while heating at 60° C. to progress a reaction, and after the reaction was finished, the result was extracted using a sodium thiosulfate solution and dichloromethane. The organic layer was dried using sodium sulfate, and purified to solids using methanol. Compound 7 (4.5 g, yield 61%) was obtained therethrough. (HR LC/MS/MS m/z calculated for C₄₁H₁₉BCl₄F₆I₂N₂S₃ (M+): 1153.7551; found: 1153.7561)

Example 1

A first solution was prepared by dissolving Compound 1 (maximum absorption wavelength 521 nm, maximum emission wavelength 535 nm, full width at half maximum 25 nm in toluene solution), an organic fluorescent substance, in a xylene solvent.

A second solution was prepared by dissolving a thermoplastic resin SAN (styrene-acrylonitrile-based) in a xylene solvent. The first solution and the second solution were homogeneously mixed so that the amount of the organic fluorescent substance was 0.5 parts by weight based on 100 parts by weight of the SAN. The solid content in the mixed solution was 20% by weight and viscosity was 200 cps. This solution was coated on a PET substrate, and the result was dried to prepare a color conversion film.

A luminance spectrum of the prepared color conversion film was measured using a spectroradiometer (SR series of TOPCON Corporation). Specifically, the prepared color conversion film was laminated on one surface of a light guide plate of a backlight unit including an LED blue backlight (maximum emission wavelength 450 nm) and the light guide plate, and after laminating a prism sheet and a DBEF film on the color conversion film, a luminance spectrum of the film was measured. When measuring the luminance spectrum, an initial value was set so that the brightness of the blue LED light was 600 nit based on without the color conversion film.

Example 2

An experiment was performed in the same manner as in Example 1 except that Compound 2 (maximum absorption wavelength 514 nm, maximum emission wavelength 528 nm, full width at half maximum 28 nm in toluene solution) was used instead of Compound 1.

Example 3

An experiment was performed in the same manner as in Example 1 except that Compound 3 (maximum absorption wavelength 517 nm, maximum emission wavelength 531 nm, full width at half maximum 27 nm in toluene solution) was used instead of Compound 1.

Example 4

An experiment was performed in the same manner as in Example 1 except that Compound 4 (maximum absorption wavelength 531 nm, maximum emission wavelength 540 nm, full width at half maximum 28 nm in toluene solution) was used instead of Compound 1.

Example 5

An experiment was performed in the same manner as in Example 1 except that Compound 5 (maximum absorption wavelength 513 nm, maximum emission wavelength 527 nm, full width at half maximum 23 nm in toluene solution) was used instead of Compound 1.

Example 6

An experiment was performed in the same manner as in Example 1 except that Compound 6 (maximum absorption wavelength 589 nm, maximum emission wavelength 622 nm, full width at half maximum 40 nm in toluene solution) was used instead of Compound 1.

Example 7

An experiment was performed in the same manner as in Example 1 except that Compound 7 (maximum absorption wavelength 595 nm, maximum emission wavelength 632 nm, full width at half maximum 45 nm in toluene solution) was used instead of Compound 1.

Comparative Example 1

An experiment was performed in the same manner as in Example 1 except that the following mPhBODIPY (maximum absorption wavelength 503 nm, maximum emission wavelength 516 nm, full width at half maximum 26 nm in toluene solution) was used instead of Compound 1.

Comparative Example 2

An experiment was performed in the same manner as in Example 1 except that the following pPhBODIPY (maximum absorption wavelength 570 nm, maximum emission wavelength 613 nm, full width at half maximum 42 nm in toluene solution) was used instead of Compound 1.

Comparative Example 3

An experiment was performed in the same manner as in Example 1 except that the following spiro-BODIPY (maximum absorption wavelength 505 nm, maximum emission wavelength 512 nm, full width at half maximum 25 nm in toluene solution) was used instead of Compound 1.

Film emission wavelength (maximum emission wavelength and full width at half maximum), quantum yield and Abs intensity (absorption intensity) of the color conversion films according to Examples 1 to 7 and Comparative Examples 1 to 3 are as shown in the following Table 1.

TABLE 1 Film Emission Wavelength Abs λ_(max) FWHM Quantum Intensity (nm) (nm) Yield (%) (1000 hr, %) Example 1 Compound 1 535 25 88 98.5 Example 2 Compound 2 528 28 91 98.1 Example 3 Compound 3 531 27 93 98.2 Example 4 Compound 4 540 28 58 83.0 Example 5 Compound 5 527 23 90 97.9 Example 6 Compound 6 622 40 78 98.1 Example 7 Compound 7 632 45 45 85.1 Comparative mPhBODIPY 530 45 91 91.2 Example 1 Comparative pPhBODIPY 605 58 75 93.0 Example 2 Comparative Spiro- 512 25 28 96.2 Example 3 BODIPY

According to Table 1, it was identified that the color conversion films according to Examples 1 to 7 generally had higher quantum yield and more superior stability compared to the comparative examples. Particularly, Examples 2, 3 and 5 had quantum yield of 90% or greater and Examples 1 to 3, 5 and 6 had absorption intensity of 97% or greater. In addition, by the maximum emission wavelength of each of the color conversion films of Examples 1 to 6 having a full width at half maximum of 40 nm or less, excellent color gamut was obtained. 

The invention claimed is:
 1. A compound represented by Chemical Formula 1:

wherein, in the Chemical Formula 1, X is a direct bond; S; or O; X₁ and X₂ are the same as or different from each other, and each independently O or S; R₁ and R₆ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a substituted or unsubstituted alkyl group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted aryloxy group; or a substituted or unsubstituted heteroaryl group; R₃ and R₄ are the same as or different from each other, and each independently a substituted or unsubstituted aryl group; R₂ and R₅ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; —C(═O)OR_(A); —OC(═O)R_(B); a substituted or unsubstituted aryl group; or a substituted or unsubstituted heteroaryl group; R₇ is a substituted or unsubstituted aryl group; a substituted or unsubstituted aryloxy group; a substituted or unsubstituted arylthioxy group; or a substituted or unsubstituted heteroaryl group; R₈, R₁₀ to R₁₃ and R₁₅ are the same as or different from each other, and each independently hydrogen; deuterium; or a halogen group; R₉ and R₁₄ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; a nitro group; —C(═O)OR_(C); —OC(═O)R_(D); a substituted or unsubstituted alkyl group; a substituted or unsubstituted cycloalkyl group; a substituted or unsubstituted aryl group; or a substituted or unsubstituted heteroaryl group; and R_(A) to R_(D) are the same as or different from each other, and each independently a substituted or unsubstituted alkyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted heteroaryl group; or a substituted or unsubstituted coumarin group.
 2. The compound of claim 1, wherein X₁ and X₂ are O, and R₃ and R₄ are the same as or different from each other and each independently an aryl group unsubstituted or substituted with one or more substituents selected from the group consisting of a halogen group, a cyano group and an alkyl group.
 3. The compound of claim 1, wherein X₁ and X₂ are S, and R₃ and R₄ are the same as or different from each other and each independently an aryl group unsubstituted or substituted with one or more substituents selected from the group consisting of a halogen group and an alkyl group.
 4. The compound of claim 1, wherein R₁ and R₆ are the same as or different from each other, and each independently hydrogen; deuterium; a cycloalkyl group unsubstituted or substituted with an alkyl group; or an aryloxy group unsubstituted or substituted with a halogen group.
 5. The compound of claim 1, wherein R₂ and R₅ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; a cyano group; —C(═O)OR_(A); —OC(═O)R_(B); or an aryl group unsubstituted or substituted with a haloalkyl group; and R_(A) and R_(B) are as defined in claim
 1. 6. The compound of claim 1, wherein R₇ is an aryl group unsubstituted or substituted with one or more substituents selected from the group consisting of an alkyl group, an alkoxy group and a haloalkyl group; an aryloxy group unsubstituted or substituted with one or more substituents selected from the group consisting of a cyano group and an alkyl group; or a substituted or unsubstituted dibenzofuran group.
 7. The compound of claim 1, wherein R₉ and R₁₄ are the same as or different from each other, and each independently hydrogen; deuterium; a halogen group; or a substituted or unsubstituted alkyl group.
 8. The compound of claim 1, wherein the compound represented by Chemical Formula 1 is any one of the following compounds:

wherein iPr is isopropyl; and tBu is tert-butyl.
 9. A color conversion film comprising: a resin matrix; and at least one compound of claim 1 dispersed into the resin matrix.
 10. The color conversion film of claim 9, wherein a content of the compound is from 0.001% by weight to 10% by weight based on the total weight of the color conversion film.
 11. A backlight unit comprising the color conversion film of claim
 9. 12. A display apparatus comprising the backlight unit of claim
 11. 13. The color conversion film of claim 9, wherein a material for the resin matrix is a thermoplastic polymer or a thermocurable polymer.
 14. The color conversion film of claim 13, wherein the material for the resin matrix is at least one resin selected from a poly(meth)acryl-based resin, a polycarbonate (PC)-based resin, a polystyrene (PS)-based resin, a polyarylene (PAR)-based resin, a polyurethane (PU)-based resin, a styrene-acrylonitrile (SAN)-based resin, a polyvinylidene fluoride (PVDF)-based resin, and a modified polyvinylidene fluoride (modified-PVDF)-based resin.
 15. The compound of claim 1, wherein R₁ and R₆ are the same as or different from each other, and each independently hydrogen; deuterium; a cyclohexyl group unsubstituted or substituted with an alkyl group; or a C6 to C20 aryloxy group unsubstituted or substituted with a halogen group.
 16. The compound of claim 1, wherein R₇ is a phenyl group unsubstituted or substituted with one or more substituents selected from the group consisting of an alkyl group, a haloalkyl group and an alkoxy group; an aryloxy group unsubstituted or substituted with one or more substituents selected from the group consisting of a cyano group and an alkyl group; or a dibenzofuran group. 